The dynamic chromatographic behavior of tri-o-thymotide on HPLC chiral stationary phases.
نویسندگان
چکیده
The interconverting stereoisomers of tri-o-thymotide have been separated by HPLC on chiral stationary phases and the temperature dependence of the dynamic chromatographic patterns has been interpreted in terms of exchange between enantiomeric propeller and helical conformations. Computed low energy structures and CD spectra were used in absolute configuration assignment.
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عنوان ژورنال:
- Chemical communications
دوره 48 26 شماره
صفحات -
تاریخ انتشار 2012